杂原子
阳极
X射线光电子能谱
兴奋剂
碳纤维
材料科学
化学工程
纳米技术
无机化学
化学
复合材料
电极
工程类
光电子学
有机化学
戒指(化学)
物理化学
复合数
作者
Baofeng Yang,Sitong Liu,Yu. V. Fedoseeva,А. В. Окотруб,Анна A. Макарова,Xiaolong Jia,Ji Zhou
标识
DOI:10.1016/j.jpowsour.2021.229700
摘要
Heteroatom-doping is an effective way to regulate the electronic structure of carbon so as to improve their Na-ion storage capability. In all kinds of heteroatoms, selenium (Se)-doping has rarely been investigated even though Se has unique physicochemical properties. Herein, we report a facile fabrication of Se/N-codoped carbon nanosheets (N/Se-CNs) with 10 at% N and 2 at% Se by an oxidation-selenization process. The synchrotron X-ray photoelectron spectroscopy (XPS) measurements indicate that Se doping can significantly change the electronic structures of carbon nanosheets, because Se can act as stronger electron-withdrawing units for Na storage compared with C and N. Therefore, Se can better play the role of improving the conductivity and wettability of the carbon materials. And Se atoms effectively enlarge the interlayer distance of carbon nanosheets to enhance the Na-ion diffusion kinetics and also generate extra active sites for Na-ion storage. Served as anode materials for SIBs, the N/Se-CNs delivers higher specific capacity and better rate capability compared with only N-doped carbon nanosheets. Therefore, Se-doping is an effective way for improvement of Na-storage capability of carbon materials. Moreover, this work should provide a new pathway for design of carbons doped by heteroatoms with large atomic size towards excellent Na-ion storage.
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