光催化
煅烧
反应性(心理学)
面(心理学)
Crystal(编程语言)
材料科学
氧化钴
氧化物
傅里叶变换红外光谱
钴
化学工程
催化作用
纳米晶
光化学
化学
纳米技术
有机化学
五大性格特征
心理学
替代医学
程序设计语言
冶金
人格
病理
工程类
社会心理学
医学
计算机科学
作者
Ziyi Feng,Xingwang Zhu,Jinman Yang,Kang Zhong,Zhifeng Jiang,Qing Yu,Yanhua Song,Hua Ye,Huaming Li,Hui Xu
标识
DOI:10.1016/j.apsusc.2021.151848
摘要
Highly specific exposed to different crystal facets remarkably affect the CO2 reduction photoreactivity. Thereby, we give examples of well-interpretated Co3O4 nanosheets, which dominating with respective facets, {1 1 2} and {1 1 1}, to explore the reactivity of the photocatalysis's special exposed crystal facets in the photocatalytic CO2 reduction. The true photoreactivity of Co3O4-{1 1 2} were testified to be remarkably higher than Co3O4-{1 1 1} for both CO evolution and CH4 production reactions. Further photoelectrochemical detection studies have confirmed that the different reactivity is not only due to the different morphologies of the calcined materials under different temperature conditions, but controlled by the different exposing facets, giving rise to the photogenerated carriers and effective space separation. Under the calcination condition of 673 K, CO and CH4 evolution rates of Co3O4-{1 1 2} reached 96.4 and 18.94 μmol·g−1·h−1. The mechanism of the reaction was further confirmed by in-situ fourier transform infrared spectroscopy and DFT calculation. Effective separation of photogenerated carriers and specific flaky shapes, crystal facets, and surface atomic arrangement all contribute to the high activity of the carefully designed Co3O4 photocatalysis.
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