Carbon‐Based Composites as Anodes for Microbial Fuel Cells: Recent Advances and Challenges

Abstract Owing to the low price, chemical stability and good conductivity, carbon‐based materials have been extensively applied as the anode in microbial fuel cells (MFCs). In this review, apart from the charge storage mechanism and anode requirements, the major work focuses on five categories of carbon‐based anode materials (traditional carbon, porous carbon, nano‐carbon, metal/carbon composite and polymer/carbon composite). The relationship is demonstrated in depth between the physicochemical properties of the anode surface/interface/bulk (porosity, surface area, hydrophilicity, partical size, charge, roughness, etc.) and the bioelectrochemical performances (electron transfer, electrolyte diffusion, capacitance, toxicity, start‐up time, current, power density, voltage, etc.). An outlook for future work is also proposed.