金红石
锐钛矿
化学
催化作用
光催化
反应性(心理学)
纳米复合材料
吸附
光化学
热液循环
相(物质)
选择性
异质结
纳米颗粒
化学工程
纳米技术
材料科学
物理化学
有机化学
工程类
病理
替代医学
医学
光电子学
作者
Eduardo Morais,Colin O’Modhrain,K. Ravindranathan Thampi
标识
DOI:10.1016/j.jcat.2021.08.007
摘要
The incorporation of TiO2 (at two different loadings) with plasmonic RuO2 nanoparticles (with an average size of (3 ± 0.7) nm) to form nanocomposites is studied. XRD results show that RuO2 is formed in the rutile phase, while high levels of TiO2 forms the rutile phase and lower levels form the anatase phase. XRD also confirms doping of TiO2 with Ru atoms and vice versa (doping of RuO2 with Ti atoms) in the nanocomposites. The effect of TiO2 incorporation on the reactivity of RuO2 in the artificial photosynthesis reaction under visible light (which TiO2 cannot absorb) is dramatic. The activities of the catalysts (once TiO2 is included in the composite) significantly increase, and the selectivity of the reactions change with the formation of CH4 and adsorbed hydrocarbonaceous species found alongside the CO + O2 formed over pure RuO2 catalysts. This is ascribed to the generation of a heterojunction interface in the composite material. Following the absorption of visible light, hot electrons (derived from the RuO2 plasmon) become sufficiently energetic to be transferred to the TiO2 CB. From this level the electrons can generate nascent hydrogen which subsequently reacts with (and reduces) adsorbed CO2 molecules.
科研通智能强力驱动
Strongly Powered by AbleSci AI