光电流
异质结
材料科学
光催化
化学工程
复合数
降级(电信)
氧气
催化作用
载流子
电化学
纳米技术
电极
光电子学
复合材料
化学
电子工程
物理化学
有机化学
工程类
作者
Minghui Sun,Xiaoguang Wang,Zhiquan Chen,Muthu Murugananthan,Yong Chen,Yanrong Zhang
标识
DOI:10.1016/j.apcatb.2020.119061
摘要
In this study, an electrochemical reduction strategy was adopted to introduce oxygen vacancies (OVs) into BiVO4/WO3/TiO2 nanotubes composite film (R-BiVO4/WO3/TNTs), and the newly generated OVs were mainly distributed on BiVO4. Desired concentration and distribution of the OVs were achieved by optimizing the reduction potential and duration. By introducing the reduced BiVO4, the inherent reaction mechanism dominated by OH and photogenerated hole was changed into the reaction dominated by O2− and hole, thereby improving the stability of the OVs in the catalytic process. The construction of heterojunction with the stabilized OVs had a significant contribution towards charge carrier separation and transmission in the material, and especially the stability of the performance. Thus, the R-BiVO4/WO3/TNTs exhibited a 28 times higher photocurrent intensity than the pristine BiVO4/WO3/TNTs, and the one-time purification experiment further confirmed the excellent performance and persistent nature of R-BiVO4/WO3/TNTs composite film in the actual treatment of VOCs.
科研通智能强力驱动
Strongly Powered by AbleSci AI