Bond strength of different wood-plastic hybrid components prepared through back injection moulding

Golf tees with a plastic head and wooden shaft were prepared by back injection moulding of a beech wood (Fagus sylvatica) shaft with different polymers (i.e. ionomer, polypropylene, and polyamide). In order to facilitate adhesion between the polymer melt and the wood surface, the wooden shafts were pre-treated with different primer substances, including a commercially available primer for ABS edges, a 10% solution of alkyl ketene dimer (AKD) in toluene and tumbling lacquer. The mechanical strength of the wood-plastic interphase was characterized by applying a pull-out test. Bond strength values of more than 9 N/mm² were observed for polyamide, whereas ionomer and polypropylene specimens achieved values between 0.7 and 3.8 N/mm². Surprisingly, the used primers failed to improve interfacial adhesion with the exception of the ionomer sample pre-treated with the commercial ABS-primer. Although light microscopy and SEM revealed some differences in the penetration behaviour of the different polymers as well as in the extent of plastic wood deformation imposed during injection moulding, the chemical nature of the polymer seems to be the most important determinant for the bond strength of wood-plastic hybrid components.