热固性聚合物
环氧树脂
固化(化学)
材料科学
单体
共聚物
环氧化物
生物降解
聚合物
双功能
马来酸酐
高分子化学
有机化学
复合材料
化学
催化作用
作者
Bungo Ochiai,Miharu Yashima,Katsutaka Soegawa,Yoshimasa Matsumura
出处
期刊:ACS Macro Letters
[American Chemical Society]
日期:2022-12-25
卷期号:12 (1): 54-58
被引量:10
标识
DOI:10.1021/acsmacrolett.2c00626
摘要
Biodegradable epoxy thermosets were developed by curing through copolymerization of a diglycidate monomer, a bifunctional epoxide bearing ester linkages, with cyclic acid anhydrides as a biosafe thermosetting system. The cured products of the glycidate exhibit high adhesiveness, identical to analogous cured products of conventional glycidyl ethers. Even an inert cycloolefin polymer and polyimide can be adhered. The cured products of the glycidate can be hydrolytically and biologically degraded. The biodegradation of the glycidate thermoset in compost completely proceeded within 2 weeks.
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