杂原子
材料科学
锂(药物)
阳极
掺杂剂
兴奋剂
碳纤维
化学工程
纳米技术
电极
复合材料
光电子学
有机化学
戒指(化学)
物理化学
化学
医学
复合数
工程类
内分泌学
作者
Decai Qin,Lei Wang,Xian‐Xiang Zeng,Jian Shen,Fei Huang,Guiyin Xu,Meifang Zhu,Zhihui Dai
标识
DOI:10.1016/j.ensm.2022.10.049
摘要
Engineering the structure and increasing the near-surface reaction of carbon materials can show unexpected effects for designing high-rate capability of lithium, sodium-ion batteries (LIBs, SIBs). The edge heteroatom-doping strategy of carbon materials can significantly enhance the Li+ and Na+ adsorption energy. However, achieving ultrahigh content of edge heteroatoms doping is still a great challenge due to the difficulty in tailoring the heteroatom dopant construction. Herein, a facile synthesis method was proposed to design the ultrahigh content of edge nitrogen/oxide/sulfur doping turbostratic carbon (NOS-TC) materials for high-performance LIBs and SIBs. The prepared NOS-TC800 has a 3D microstructure, a large defect spacing, and an ultrahigh content (21.70 at%) of edge-N, O, S tri-doping. The NOS-TC800 anode displays a high-rate capability, and accompanied by an ultralong cycling life (214.9 mAh g − 1 after 3500 cycles at 10 A g − 1 in LIBs, 159.6 mAh g − 1 after 3000 cycles at 5 A g − 1 in SIBs). The NOS-TC800 anode-based full cell has a high energy density of 212 Wh kg−1 for LIBs and 142 Wh kg−1 for SIBs. The strategy of tailored architecture and high-content edge heteroatom-doping demonstrates that it is promising to achieve high-rate capability and energy density for LIBs and SIBs.
科研通智能强力驱动
Strongly Powered by AbleSci AI