Chlorine-mediated electrochemical advanced oxidation process for ammonia removal: Mechanisms, characteristics and expectation

Chlorine-Mediated Electrochemical Advanced Oxidation (Cl-EAO) technology is a promising approach for ammonia removal from wastewater due to its numerous advantages, including small infrastructure, short processing time, easy operation, high security, and high nitrogen selectivity. This paper provides a review of the ammonia oxidation mechanisms, characteristics, and anticipated applications of Cl-EAO technology. The mechanisms of ammonia oxidation encompass breakpoint chlorination and chlorine radical oxidation, although the contributions of active chlorine, Cl , and ClO remain uncertain. This study critically examines the limitations of existing research and suggests that a combination of determining free radical concentration and simulating a kinetic model would help elucidate the contributions of active chlorine, Cl , and ClO to ammonia oxidation. Furthermore, this review comprehensively summarizes the characteristics of ammonia oxidation, including kinetic properties, influencing factors, products, and electrodes. The amalgamation of Cl-EAO technology with photocatalytic and concentration technologies has the potential to enhance ammonia oxidation efficiency. Future research should concentrate on clarifying the contributions of active chlorine, Cl , and ClO to ammonia oxidation, the production of chloramines and other byproducts, and the development of more efficient anodes for the Cl-EAO process. The main objective of this review is to enhance the understanding of the Cl-EAO process. The findings presented herein contribute to the advancement of Cl-EAO technology and provide a foundation for future studies in this field. • Cl-EAO technology for ammonia removal was critically reviewed. • Cl-EAO mechanism included active chlorine and chlorine radical oxidation. • Contributions of active chlorine and chlorine radical remain unclear. • Ammonia oxidation was greatly impacted by electrode and reaction conditions. • Cl-EAO efficiency can be improved through combination with other technologies.