过电位
分解水
异质结
材料科学
纳米片
镍
化学工程
退火(玻璃)
电化学
电子转移
光电子学
电极
催化作用
纳米技术
化学
冶金
光化学
物理化学
光催化
生物化学
工程类
作者
Shuai Niu,Heng Liu,Hao Luo,Yuyun Chen,Hyeon-Jin Sun,Hugang Li
标识
DOI:10.1016/j.ijhydene.2023.04.247
摘要
Developing heterostructures electrocatalysts was a promising method to improve the water splitting efficiency. However, due to the difficulty of synthesis, such low-cost and high-activity heterostructures electrocatalysts have not been developed. In this work, Ni3Se2/NiSe heterostructure nanosheets with rich-phase boundaries were synthesized by soaking at room temperature and annealing treatment using nickel foam as both Ni source and substrate. Such a nanosheet-like Ni3Se2/NiSe heterostructure could expose more active sites and efficient mass transfer at solid-liquid-gas three-phase interfaces, which exhibits a lower overpotential of 336 mV at 100 mA cm−2 and exceptional stability over 80 h at the current density of 300 mA cm−2 for OER in alkaline solution. Furthermore, the heterostructures electrode implements solar-driven water with a high solar-to-hydrogen efficiency of 18.3%. This heterostructure strategy might be a major breakthrough for improving the transition metal selenides and designing high-active and stable catalysts for electrochemical water oxidation.
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