Solid-Phase Pyrolysis Synthesis of Highly Fluorescent Nitrogen/Sulfur Codoped Graphene Quantum Dots for Selective and Sensitive Diversity Detection of Cr(VI)

In this study, a simple one-step solid-phase pyrolysis synthesis procedure was employed to prepare N and S codoped highly fluorescent graphene quantum dots (N/S-GQDs). The as-synthesized quantum dot showed λ_excitation-dependent blue fluorescence (FL) emission with a relative quantum yield of about 22% and displayed good biocompatibility, high water dispersibility, and excellent stability under extreme conditions (i.e., ionic strength, pH, and temperature). The potential applicability of the as-synthesized quantum dot was tested by employing solution- and paper-based FL detection modes for Cr(VI) detection. The proposed solution- and paper-based FL sensors showed lower limit of detection (LOD) values of 0.01 and 0.4 μM, respectively. The as-constructed paper- and solution-based FL sensors proved the feasibility of sensitive, cost-effective, and on-site detection of Cr(VI).