化学
反应性(心理学)
组合化学
有机化学
立体化学
医学
病理
替代医学
作者
Federica Rogati,Chiara Maioli,Gianluigi Lauro,Diego Caprioglio,Daniela Imperio,Erika Del Grosso,Bruno Botta,Luisa Mannina,Giuseppe Bifulco,Cinzia Ingallina,Alberto Minassi
标识
DOI:10.1021/acs.jnatprod.3c00067
摘要
The discovery of new bioactivities is closely related to the generation of novel scaffolds, and in the past few years different strategies have been proposed to obtain unknown architectures from the manipulation of known compounds. In the present study, we exploited a vintage photochemical approach for the discovery of an unexpected pathway of reactivity related to Δ1-3-oxo-pentacyclic triterpenic acids gaining access to a new class of natural–unnatural 5(10→1)abeo-pentacyclic triterpenic acids.
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