Controllable Modulation of Trapped Carriers in Mechano/Thermo Dual‐Responsive Particles for Advanced Stress‐Encoded Information Storage

Abstract Mechanoluminescence (ML) is a fascinating phenomenon with diverse applications in pressure sensing, damage detection, and stress distribution visualization. However, most ML materials exhibit instantaneous photon emission that requires real‐time recording with a photodetector, and thereby circumscribing their applicability predominantly to real‐time stress‐sensing scenarios. In this work, a novel method is introduced for non‐real‐time stress sensing utilizing Li0.1Na0.9NbO3:Pr3+ phosphor, which allows for the retrieval of pressure location and intensity even 20 days after the event. The influence of heat and pressure on the trap depth distribution is analyzed using thermoluminescence (TL) and ML measurements, and it is proved that both heat and pressure release the captured electrons in the same traps. Leveraging the intricate competition between mechanical and thermal detrapping processes, stress information can be accessed through TL imaging. Furthermore, an algorithm is proposed based on this phenomenon to authenticate the stress information. This research not only advances the fundamental understanding of ML phenomena but also introduces a novel approach for applications such as mechano‐history indicators, security papers, and advanced data storage systems.