聚乳酸
应力松弛
韧性
复合材料
材料科学
压力(语言学)
放松(心理学)
聚合物
医学
语言学
蠕动
哲学
内科学
作者
Chao Lei,Weixing Xu,Bi Shi,Yunhang Zeng
标识
DOI:10.1016/j.indcrop.2024.118160
摘要
Polylactic acid (PLA) is a typical bio-based polymer derived from crops. Its widespread application has been limited due to stress relaxation and brittleness. Here, a sustainable strategy to simultaneously improve the anti-stress relaxation and toughness of PLA biocomposites was proposed by blending PLA with epoxidized soybean oil (ESO)-modified collagen fiber (CF, ESO-CF). ESO enhanced the interfacial interaction between ESO-CF and PLA by constructing cross-linked networks in ESO-CF/PLA. Comparative analyses of stress relaxation and fracture behaviors were conducted between ESO-CF/PLA and pure PLA. The stress–strain curves of ESO-CF/PLA showed lower peak stress reduction rate (1% strain; 27.1%) and irrecoverable strain (zero stress; 0.3%) after 10 cycles compared with those of pure PLA, indicating that the introduction of ESO-CF greatly improved the anti-stress relaxation of PLA. Moreover, the elongation at break and the impact strength of ESO-CF/PLA were 301.6% and 78.9% higher than those of pure PLA, respectively, indicating that ESO-CF improved the toughness of PLA. The enhancements were mainly attributed to the naturally multidirectional and hierarchical structure of ESO-CF and the effective interfacial interaction between ESO-CF and PLA. This work provides insights into the development of PLA biocomposites with enhanced mechanical properties by blending with vegetable oil-modified natural fibers.
科研通智能强力驱动
Strongly Powered by AbleSci AI