Waste derived ash as catalysts for the pyrolysis-catalytic steam reforming of waste plastics for hydrogen-rich syngas production

Ash derived from the oxidation of waste tire and processed municipal solid waste in the form of refuse-derived fuel have been investigated for their potential as catalysts in the pyrolysis catalytic steam reforming of high-density polyethylene to produce hydrogen-rich syngas. The surface morphology, element distribution, pore structure and metal composition of the ashes were characterized to explore the effects of these ash properties on the catalytic process. Further work using tire ash investigated the influence of the process parameters, catalytic temperature and catalyst plastic ratio in relation to the production of hydrogen and syngas. The results showed that tire ash had a higher specific surface area and pore volume than refuse-derived fuel ash, resulting in a slightly higher hydrogen yield compared to refuse derived fuel ash. An increase in the temperature of the catalytic steam reforming process with the tire ash catalyst significantly increased the hydrogen yield from 13.3 mmol g-1plastic at 800 °C to 83.2 mmol g-1plastic at 1000 °C. At higher catalyst:plastic ratios, the higher amounts of catalyst produced no discernable increase in hydrogen. A tentative reaction mechanism in relation to waste derived ash as catalysts for the steam reforming of plastics pyrolysis volatiles is provided.