塔菲尔方程
催化作用
材料科学
共价键
电化学
化学工程
电解质
分解水
密度泛函理论
共价有机骨架
纳米技术
多孔性
化学
光催化
电极
物理化学
计算化学
有机化学
复合材料
工程类
作者
Chun-an MA,Haiyan He,Jianhuang Qin,Lang Luo,Yaqi Lan,Jian Zhang,Lu Yang,Quanguo Jiang,Huajie Huang
标识
DOI:10.1002/sstr.202300279
摘要
Electrochemical water splitting is long regarded as a green and feasible pathway to realize the scalable hydrogen production, while the overall hydrogen evolution reaction (HER) efficiency is largely dependent on the electrocatalytic ability of the cathode catalysts. Herein, the in situ growth of hydrazone‐linked covalent organic framework (COF‐42) nanocrystals with a unique nanoflower‐shaped morphology on 2D ultrathin Ti 3 C 2 T x MXene nanosheets (COF/Ti 3 C 2 T x ) is achieved through a convenient and robust stereoassembly strategy. Strikingly, the marriage of COF‐42 and Ti 3 C 2 T x nanosheets not only offers multiscale porous channels for the fast transportation of electrolyte and electrons, but also enables the full exposure and activation of numerous catalytically active centers. As a consequence, the optimized COF/Ti 3 C 2 T x nanoarchitecture displays exceptional HER properties in terms of a very low onset potential of 19 mV, a small Tafel slope of 50 mV dec −1 as well as reliable long‐term durability, which are comparable to those of commercial Pt/C catalyst. Density functional theory calculations further disclose that the rational combination of COF‐42 with Ti 3 C 2 T x provides more diversified active positions with appropriate Δ G H values, thus leading to a boosted hydrogen generation rate.
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