Preparation of novel clay/chitosan/ZnO bio-composite as an efficient adsorbent for tannery wastewater treatment

This study focuses on the preparation of an activated clay/chitosan/ZnO bio-composite using solvent casting method. Clay was activated through microwave radiation using 1 M H2SO4 at a minimum liquid to solid ratio (L/S). Chitosan was extracted from waste prawn shell and ZnO nanoparticles (ZnO-NPs) were synthesized from zinc acetate di-hydrate (Zn (CH3CO2)2·2H2O) using the sol-gel method. The produced bio-composite were characterized using FT-IR, TGA, XRD and SEM. Response surface methodology (RSM) was used for experimental design to find out the optimum conditions, e.g., pH of the solution, dosage of adsorbent and contact time for the removal of methylene blue (MB) and Cr (VI) using MINITAB 18.1 software. The optimum conditions obtained for the highest removal of MB were pH 9.57, dosage 55.44 mg and contact time 114.09 min. Similarly, for the highest removal of Cr (VI) the optimum conditions were pH 3.75, dosage 67.42 mg and contact time 111.27 min. Applying these optimum conditions, the highest removal efficiency for MB and Cr (VI) was obtained at 84.21 % and 82.67 % with 9.57 mg g−1 and 10.45 mg g−1 of adsorption capacity respectively. The adsorption data were studied for both Langmuir and Freundlich isotherm. The value of maximum Langmuir sorption was (qm) 17.346 mg g−1 and 17.621 mg g−1 for MB and Cr (VI) respectively.