The use of photoreflectance spectroscopy for the assessment of modulation doped structure is discussed in this paper Direct empirical estimation of various parameters like alloy composition. built-in electric field and two dimensional electron gas concentration has been demonstrated. These parameters were estimated from the observed Franz-Keldysh oscillations in photoreflection spectrum at different temperatures in the range of 17 - 300 K Molecular beam epitaxy grown Al x Ga 1-x As/GaAs modulation doped structures have been used for this study.