材料科学
铁电性
纳米复合材料
矫顽力
多铁性
复合材料
纳米颗粒
极化(电化学)
泄漏(经济)
纳米技术
光电子学
电介质
凝聚态物理
物理化学
经济
宏观经济学
化学
物理
作者
Lingfang Xu,Yu Zhang,Chao Gui,Hanshuo Fang,Ruilong Wang,Haibo Xiao,Shiheng Liang,Changping Yang
标识
DOI:10.1016/j.ceramint.2021.04.276
摘要
BiFeO3 has been extensively studied as an important single-phase multiferroic material at room temperature in the application fields of energy storage, data storage, spintronics, and electro-magnetic sensors. However, the high leakage current caused by the presence of lattice defects such as vacancies constrains the further development of BiFeO3. In this paper, we presented a facile method to overcome the high leakage problem via blending BiFeO3 nanoparticles into the ferroelectric copolymer PVDF-TrFE matrix and introducing a barrier layer beneath the top Pt dot electrode. The leakage current and ferroelectric characteristics of BiFeO3_PVDF-TrFE nanocomposite films were discussed comprehensively. Consequently, compared with the composites without the barrier layer, the leakage current density of the BiFeO3_PVDF-TrFE composite films reduced two orders of magnitude after coating a pure copolymer layer. Moreover, the remnant ferroelectric polarization reached ~14 μC cm−2 for a moderate weight content (25 wt%) of BiFeO3 nanoparticle in the blends, with a remarkably smaller coercive electric field than that of pure PVDF-TrFE films. An electrical conduction blocking mechanism was established to elucidate the optimized electric and ferroelectric properties of nanocomposite films.
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