材料科学
3D打印
复合材料
铸造
聚合物
溶解
造型(装饰)
压缩成型
3d打印
化学工程
模具
医学
工程类
生物医学工程
作者
Yunchao Jia,Fei Ling,Jiaru Qian,Qianqian Chen,Zhiwei Zhao,Yilong Li
出处
期刊:ACS Macro Letters
[American Chemical Society]
日期:2023-05-17
卷期号:12 (6): 719-724
被引量:4
标识
DOI:10.1021/acsmacrolett.3c00116
摘要
Rigid 3D printing materials often get defects such as cavities, voids, holes, or gaps when suffering from impact forces. Fast self-healing of these damages without bulk temperature increase is always desired. Besides, the recycling of dynamically cross-linked polymers was usually focused on solvent- or heat-assisted strategies such as compression molding and dissolution-casting, which restricts the geometrical diversity of recycled materials and may cause environmental issues. Here we report a rigid photocuring 3D printing material that can heal its cave-like damage quickly under UV light based on the dynamic urea bond. Besides, after grounding the printed objects into powders and directly refilling them into new printing resin, the re-3D printed objects show similar mechanical properties to the original materials without any post-treatment.
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