Covalent-Coordination-Dual-Driven In Situ Modular Assembly of 12-Connected Nickel-Based Metal–Organic Frameworks

as a highly efficient and stable heterogeneous photocatalyst, achieving a yield of up to 99% in a visible-light-driven cross-dehydrogenative coupling reaction with excellent recyclability. This work offers a new platform for the precise and sustainable construction of highly stable, functionally advanced MOFs, highlighting the power of synergistic covalent-coordination-dual driven assembly in materials design.