阳极
法拉第效率
成核
复合数
碳纳米管
枝晶(数学)
金属
电极
化学
材料科学
极限抗拉强度
化学工程
纳米技术
复合材料
冶金
有机化学
物理化学
工程类
数学
几何学
作者
Xin He,Song Jin,Licheng Miao,Yanfei Cai,Yunpeng Hou,Haixia Li,Kai Zhang,Zhenhua Yan,Jun Chen
标识
DOI:10.1002/anie.202006783
摘要
Abstract Sodium metal is a promising anode, but uneven Na deposition with a dendrite growth seriously impedes its application. Herein, a fibrous hydroxylated MXene/carbon nanotubes (h‐Ti 3 C 2 /CNTs) composite is designed as a scaffold for dendrite‐free Na metal electrodes. This composite displays fast Na + /electron transport kinetics and good thermal conductivity and mechanical properties. The h‐Ti 3 C 2 contains abundant sodiophilic functional groups, which play a significant role in inducing homogeneous nucleation of Na. Meanwhile, CNTs provide high tensile strength and ease of film‐forming. As a result, h‐Ti 3 C 2 /CNTs exhibit a high average Coulombic efficiency of 99.2 % and no dendrite after 1000 cycles. The h‐Ti 3 C 2 /CNTs/Na based symmetric cells show a long lifespan over 4000 h at 1.0 mA cm −2 with a capacity of 1.0 mAh cm −2 . Furthermore, Na‐O 2 batteries with a h‐Ti 3 C 2 /CNTs/Na anode exhibit a low potential gap of 0.11 V after an initial 70 cycles.
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