化学
磺酰
试剂
联氨(抗抑郁剂)
亚胺
烷基
自由基引发剂
氮气
组合化学
药物化学
光化学
有机化学
高分子化学
催化作用
单体
聚合物
色谱法
作者
Yu-Shi Jiang,Shanshan Li,Xue-Ling Luo,Li-Ning Chen,Dan‐Na Chen,Peng-Ju Xia
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-08-29
卷期号:25 (36): 6671-6676
被引量:3
标识
DOI:10.1021/acs.orglett.3c02533
摘要
In this study, a metal-free difunctionalization strategy for diazenes was developed using a range of bifunctionalization reagents. This strategy involves a unique N(sp3)–N(sp2) radical coupling between the hydrazine radical and the imine radical. More than 30 triazane core motifs were constructed by installing imines and various functional groups, including alkyl, phenyl, cyanoalkyl, and sulfonyl groups, on both ends of the nitrogen–nitrogen bond of diazenes in an efficient manner.
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