材料科学
乳状液
阳极
硅酮
电解质
硅油
复合材料
涂层
有机硅树脂
化学工程
锂离子电池
热解
陶瓷
锂(药物)
电化学
图层(电子)
硅
电池(电)
碳纤维
电极
冶金
复合数
化学
医学
功率(物理)
物理
物理化学
量子力学
工程类
内分泌学
作者
Eunjeong Seok,Minsu Choi,Dohyub Park,Minjun Kim,Yong-Heum Lee,Wonchang Choi
标识
DOI:10.1016/j.jallcom.2023.172386
摘要
A submicron spherical silicon oxycarbide (SiOC) material for lithium-ion battery anodes was successfully synthesized by employing a facile synthetic strategy that used economical silicone oil as a starting material, an emulsion method, and the subsequent pyrolysis of silicone oil emulsion at 900 °C. Although most previous studies concerning silicone-oil-based SiOC exhibited irregular and uncontrollable size after synthesis, the developed emulsion-driven SiOC preparation achieved regular submicron spherical particles. Furthermore, the emulsifier used herein formed a thin carbon coating layer after the synthesis procedure and contributed to the electrochemical performance during battery operation. The spherical submicron size-controlled SiOC material had superior capacity retention compared to pristine SiOC obtained without the emulsion method, owing to the suppressed micro-cracks induced by accumulation of mechanical stress during repeated cycles and prevention of direct contact with the electrolyte by the thin carbon-coating layer.
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