阳极
材料科学
锂(药物)
枝晶(数学)
电极
镍
复合数
金属
化学工程
电化学
电流密度
金属锂
集电器
纳米技术
复合材料
冶金
化学
电解质
物理化学
内分泌学
工程类
物理
医学
量子力学
数学
几何学
作者
Tao Wei,Jiahao Liu,Pan Zhang,Guang Yang,Cheng Sun,Yanyan Zhou,Quanchao Zhuang,Yongfu Tang
标识
DOI:10.1016/j.cclet.2022.107947
摘要
For several decades, the promise of implementing of lithium (Li) metal anodes for Li batteries has been a ‘‘holy grail’’ for researchers. Herein, we have proposed a facile design of a MOF-derived Co3O4 nanoparticles modified nickel foam, i.e., Co3O4-NF, as a 3D host to achieve a uniform infusion of the molten Li. The molten Li was uniformly absorbed on the Co3O4-NF host only in 10 s due to its high Li lithiophilicity. The obtained Li-Co3O4-NF composite electrode shows high cycling stability in symmetric cells with low voltage hysteresis even at a high current density of 5 mA/cm2. The full cells of Li-Co3O4-NF/LiFePO4 can cycle for more than 500 cycles at 2C without obvious capacity decay. SEM after cycling and in situ optical microscope results suggest that the unique 3D host structure of the Li-Co3O4-NF anode plays key roles on suppressing the dendrite growth and decreasing the local current inhomogeneity. We believe this work might provide a new strategy for fabricating dendrite-free Li metal anodes and facilitate practical applications in Li batteries.
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