High‐Performance Narrowband Light‐Emitting Electrochemical Cells Enabled by Intrinsically Ionic Multi‐Resonance Thermally Activated Delayed Fluorescence Emitters

Abstract The development of efficient, bright, and stable narrowband light‐emitting electrochemical cells (LECs) has remained a challenge. Here, intrinsically ionic multi‐resonance thermally activated delayed fluorescence (MR‐TADF) emitters are reported as guest emitters for narrowband LECs, which are developed by attaching an imidazolium cation onto a typical MR‐TADF emitter. In solution, the emitters show green–blue emission peaked at 486−497 nm with small full widths at half‐maximum (FWHMs) at 24−26 nm. In doped films, they show narrowband green–blue emission with high luminescent efficiencies at ≈90%. LECs using an ionic exciplex host and the ionic MR‐TADF guest emitters show green–blue emission peaked at 494−503 nm with small FWHMs at 31−34 nm, and afford high external quantum efficiencies (EQEs) up to 10% under constant‐voltage driving. With ionic TADF small‐molecule hosts, the narrowband LECs show high EQEs up to 13.0% under constant‐voltage driving, which is the highest among all reported narrowband LECs, and afford peak brightness/EQE/half lifetime at 780 cd m −2 /5.6%/62.2 h under constant‐current driving. A long half‐lifetime of ≈630 h has further been achieved at 136 cd m −2 . The work demonstrates the great potential for the use of intrinsically ionic MR‐TADF guest emitters and ionic TADF hosts to develop efficient, bright, and stable narrowband LECs.