A review of electrospun separators for lithium‐based batteries: Progress and application prospects

Abstract Due to the limitations of the raw materials and processes involved, polyolefin separators used in commercial lithium‐ion batteries (LIBs) have gradually failed to meet the increasing requirements of high‐end batteries in terms of energy density, power density, and safety. Hence, it is very important to develop next‐generation separators for advanced lithium (Li)‐based rechargeable batteries including LIBs and Li–S batteries. Nonwoven nanofiber membranes fabricated via electrospinning technology are highly attractive candidates for high‐end separators due to their simple processes, low‐cost equipment, controllable microporous structure, wide material applicability, and availability of multiple functions. In this review, the electrospinning technologies for separators are reviewed in terms of devices, process and environment, and polymer solution systems. Furthermore, strategies toward the improvement of electrospun separators in advanced LIBs and Li–S batteries are presented in terms of the compositions and the structure of nanofibers and separators. Finally, the challenges and prospects of electrospun separators in both academia and industry are proposed. We anticipate that these systematic discussions can provide information in terms of commercial applications of electrospun separators and offer new perspectives for the design of functional electrospun separators for advanced Li‐based batteries.