假电容器
聚吡咯
电化学
材料科学
电合成
水溶液
阳极
电解质
无机化学
化学工程
阴极
电极
三氧化钼
超级电容器
化学
钼
有机化学
工程类
物理化学
作者
Ayman E. Elkholy,Timothy T. Duignan,Ruth Knibbe,Xin Zhao
标识
DOI:10.1016/j.electacta.2022.141050
摘要
Orthorhombic molybdenum trioxide (α-MoO3) is a promising electrode material for aqueous electrochemical metal-ion storage due to its unique layered structure. However, its poor electronic conductivity and instability in aqueous electrolytes hinder its applications in electrochemical energy storage. In this paper, we report on the electrosynthesis and assessment of electrochemical properties of a polypyrrole-encapsulated α-MoO3 electrode for aqueous Al3+-ion storage. This binder-free, PPy-coated α-MoO3 electrode (α-MoO3@PPy) synthesised using the electrodeposition method has a high mass loading of ∼16 mg/cm2. The α-MoO3@PPy electrode exhibites high cycling stability in 1 M aqueous AlCl3 electrolyte with capacity retention of 88% after 1000 cycles. A full electrochemical Al3+-ion pseudocapacitor cell fabricated with the α-MoO3@PPy as anode and copper hexacyanoferrate (CuHCF) as cathode demonstrates high rate capability delivering energy densities of 0.33 and 0.20 mWh/cm2 at current densities of 1 and 10 mA/cm2, respectively. In addition, this cell is stable against cycling with capacity retention of 70% after 1800 cycles. This work provides a straightforward approach to the synthesis of stable α-MoO3-based electrode materials for aqueous electrochemical energy storage.
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