Quantifying Soil Goethite/Hematite Ratios: A New Method Based on Diffuse Reflectance Spectra

Abstract Goethite/hematite ratios in soils are widely used to reconstruct past climatic changes, but their accurate measurements have remained challenging due to the matrix effect. Here we present a new method for measuring soil goethite/hematite ratios by characterizing the band position of electron pair transition (EPT) based on the diffuse reflectance spectra processed by continuum removal. We introduce a “half‐band‐area wavelength”, λ 1/2 , to characterize the EPT band position and validate the method using synthetic standards made from mixing pure goethite and hematite and four sets of goethite‐ and hematite‐free matrices derived from arid aeolian deposits and tropical saprolite. A consistent λ 1/2 ‐goethite/hematite relation across four matrices demonstrates that our method eliminates the matrix effect. We further validate our method by applying it to quantify goethite/hematite ratios in 180‐Kyr loess‐paleosol sequences and comparing the results to the reported paleoclimatic records. Our new method is promising for improving the measurement of goethite/hematite ratios in sediments.