过电位
铼
锰
电催化剂
催化作用
化学
电化学
无机化学
金属
贵金属
过渡金属
电极
有机化学
物理化学
作者
Marc Bourrez,Florian Molton,Sylvie Chardon‐Noblat,Alain Deronzier
标识
DOI:10.1002/anie.201103616
摘要
Manganese at work: carbonyl bipyridyl complexes based on manganese, a non-noble abundant and inexpensive metal, have been proved to be excellent molecular catalysts for the selective electrochemical reduction of CO(2) to CO under mild conditions. Another advantage of manganese complexes over rhenium complexes is that these catalysts operate at markedly less overpotential (0.40 V gain).
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