Dynamics of a self-propelled compound droplet

A recent experiment by Wang et al. ( Soft Matt. , vol. 17, 2021, pp. 2985–2993) shows that a self-propelled compound drop in a surfactant-laden solution can autonomously change its motion from a straight line to a spiraling trajectory, enhancing its capability for chemical detection, catalytic reaction and pollutant removal in a large fluid region. To understand the underlying physics of this peculiar motion, we develop a two-dimensional minimal model to study the swimming dynamics of a compound droplet driven by a self-generated Marangoni stress. We find that, depending on the Péclet number ( $Pe$ ) and the viscosity and volume ratios of the two compound phases, the drop can swim in a variety of trajectories, including straight lines, circles, zigzag curves and chaotic trajectories. The drop moves in circles when its two components have comparable volumes. Otherwise, it shows other types of motions depending on $Pe$ . Our simulation results for the circular motion at small $Pe$ are qualitatively comparable to the experiment. The transition between zigzag and circular trajectories is mainly determined by the orientation of high-order modes with respect to the drop's swimming direction. For most compound drops, the speed decays as $Pe^{-1/3}$ at high Péclet numbers as it does for a single-phase drop. A drop with two equal components undergoes a run-and-reorient motion due to the competition between the even and odd modes.