尖晶石
材料科学
阴极
固体氧化物燃料电池
钙钛矿(结构)
氧化物
微观结构
复合数
磁铁矿
氧气
结构精修
化学工程
分析化学(期刊)
冶金
复合材料
电极
物理化学
结晶学
晶体结构
化学
阳极
色谱法
有机化学
工程类
作者
Yuanchen Duan,Baoxiang Cao,Shiqing Li,Anqi Wu,Zhangfa Huang,Jianxin Wang,Qin Wang,Jun Yang,Wanbing Guan,Xiaopeng Qi
标识
DOI:10.1016/j.jeurceramsoc.2023.05.003
摘要
Spinel oxide cathode has made great progress in solid oxide fuel cells (SOFCs) because of its special characteristics different from perovskite. In this study, a spinel-structured SOFC cathode, CuMn1.5Ni0.5O4 (CMN), is proposed. Rietveld refinement shows that CMN takes the cubic structure of the space group of P4332. CMN shows a high conductivity of about 70.0–91.2 S cm−1 at 600–800 ºC in the air and exhibits good catalytic activity for oxygen. A symmetric cell with CMN-GDC composite cathode demonstrates a low Rp of 0.047 Ω cm2 at 800 ºC. The charge transfer of oxygen is the rate-limiting process at lower temperatures. The performance test results of the button cell with CMN-GDC composite cathode are excellent, with high power densities of 1342.4 mW cm−2 at 800 ºC. After a110h long-term test, the cell runs stably, and no microstructure damage is observed.
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