Rational Design of Rare Earth-Based Nanomaterials for Electrocatalytic Reactions

Rare earth-based nanomaterials hold great promise for applications in the electrocatalysis field owing to their unique 4f electronic structure, adjustable coordination modes, and high oxophilicity. As a cocatalyst, the location of rare earth elements can alter the intrinsic properties of support, including coordination environments, electronic structure, and structure evolution under applied potentials in a variable manner, to potentially impact catalytic performance with respect to their activity, stability, and selectivity. Therefore, a comprehensive understanding of the effects of rare earth elements' location on local structure and reaction mechanisms is a prerequisite for designing advanced rare earth-based nanomaterials. In this review, the rare earth-based nanomaterials have been categorized into three main groups based upon the location of rare earth elements in the support, namely lattice, surface, and interface structure. We initially discuss recent advances and representing breakthroughs to realize controllable synthesis of rare earth-based nanomaterials. Next, we discuss the state-of-the-art rare earth-based nanomaterials and the structure modulation strategy employed to enhance their catalytic performance. Combined with advanced characterizations, the role of rare earth elements in reaction mechanisms and structure evolution process is also discussed. Finally, we further highlight the future research directions and remaining challenges for the development of rare earth-based nanomaterials in practical applications.