Control of Reversible Oxidative Addition/Reductive Elimination of Surface-Attached Catalysts by External Electric Fields

. Our analysis indicates that these field-dependent effects are driven by changes in the permanent dipole moment, offering key insights for the design of field-controllable catalytic systems. This framework presents a novel strategy to overcome the "Goldilocks problem" of balancing competing catalytic steps by leveraging applied electric fields to dynamically tune catalytic reactivity in situ.