电催化剂
电解
电解质
材料科学
过电位
电解水
分解水
聚合物电解质膜电解
法拉第效率
制氢
化学工程
氢
电极
电化学
催化作用
化学
物理化学
工程类
有机化学
光催化
生物化学
作者
Fengning Yang,Yuting Luo,Qiangmin Yu,Zhiyuan Zhang,Shuo Zhang,Zhibo Liu,Wencai Ren,Hui‐Ming Cheng,Jiong Li,Bilu Liu
标识
DOI:10.1002/adfm.202010367
摘要
Abstract Water electrolysis is promising for industrial hydrogen production to achieve a sustainable and green hydrogen economy, but the high cost of the technology limits its market share. Developing efficient yet economic electrocatalysts is crucial to decrease the cost of electricity and electrolytic cell. Meanwhile, electrolysis in seawater electrolyte can further reduce feedstock cost. Here, a type of electrocatalyst is synthesized, where trace precious metals are strongly anchored on a corrosion‐resistive matrix. As an example, the produced Pt/Ni‐Mo electrocatalyst only needs an overpotential of 113 mV to reach an ultrahigh current density of 2000 mA cm −2 in the saline‐alkaline electrolyte, demonstrating the best performance reported thus far. It shows high activity and long durability in various electrolytes and under harsh conditions, including strong alkaline and simulated seawater electrolytes, and under elevated temperatures up to 80 ° C. This electrocatalyst is produced on a large scale at a low cost and shows good performance in a commercial membrane electrode assembly stack, demonstrating its feasibility for practical water electrolysis.
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