分子内力
质子
激发态
电子转移
化学物理
工作(物理)
电子
光谱学
原子物理学
势能面
质子耦合电子转移
超短脉冲
化学
材料科学
分子物理学
物理
物理化学
分子
热力学
核物理学
量子力学
立体化学
激光器
有机化学
作者
Paul F. Barbara,Gilbert C. Walker,Terrance P. Smith
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:1992-05-15
卷期号:256 (5059): 975-981
被引量:268
标识
DOI:10.1126/science.256.5059.975
摘要
This article primarily reviews recent work on ultrafast experiments on excited state intramolecular electron and proton transfer, with an emphasis on experiments on chemical systems that have been analyzed theoretically. In particular, those systems that have been quantitatively characterized by static spectroscopy, which provides detailed information about the reaction potential energy surface and about other parameters that are necessary to make a direct comparison to theoretical predictions, are described.
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