吸附
水溶液
聚合物
弗伦德利希方程
朗缪尔吸附模型
朗缪尔
吉布斯自由能
化学
硝基苯酚
化学工程
核化学
有机化学
热力学
物理
工程类
催化作用
作者
Qian Zhang,Chukwunonso Peter Okoli,Lingqing Wang,Tao Liang
标识
DOI:10.1080/19443994.2014.928802
摘要
Two kinds of cross-linked starch polymers were synthesized and used as adsorbent materials for the adsorption of o-nitrophenol (o-NP), p-nitrophenol (p-NP), 2,4-dinitrophenol (2,4-DNP) and 2-s-butyl-4,6-dinitrophenol (DNBP) from aqueous solutions. Results from adsorption experiments showed that the polymer 1 prepared by 4,4′-methylene-bis-phenyldiisocyanate (MDI) as cross-linking agent exhibited higher adsorption behaviors than that of the polymer 2 prepared by hexamethylene diisocyanate (HMDI). Equilibrium and thermodynamic of four nitrophenols on polymer 1 were further studied. Analyzed experimental data showed that the Freundlich model fitted the isotherm data better than the Langmuir model of the four nitrophenols onto polymer 1. The thermodynamics for the adsorption of the nitrophenols on polymer 1 were estimated in the range of 303–333 K. It has been found that the values of Gibbs free energy (ΔG) became more negative with decreasing temperature, which indicated that the adsorption process was more favorable at low temperature.
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