化学
钯
组合化学
偶联反应
联轴节(管道)
甲烷
有机化学
催化作用
反应条件
纳米技术
机械工程
工程类
材料科学
作者
Kohei Endo,Takafumi Ishioka,Takanori Shibata
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2014-08-21
卷期号:25 (15): 2184-2188
被引量:22
标识
DOI:10.1055/s-0034-1378561
摘要
The one-pot palladium-catalyzed Suzuki–Miyaura cross-coupling reaction of a diborylmethane with bromothiophene derivatives realized the synthesis of various dithienylmethane derivatives. Cyclopentadithiophenes, which are promising compounds in material science, can be obtained in good yields. The in situ generation of an unstable thienylmethylboronate is a key step for the present reaction.
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