自愈水凝胶
纳米复合材料
材料科学
韧性
复合数
氢键
石墨烯
分子
高分子化学
化学工程
复合材料
纳米技术
化学
有机化学
工程类
作者
Ke Huang,Hongyan Wu,Fan Jiang,Guozhu Shen,Lu Wang
标识
DOI:10.1016/j.polymdegradstab.2018.09.009
摘要
Smart near-infrared (NIR) light-responsive poly N-isopropylacrylamide (PNIPAM) nanocomposite hydrogels were prepared by incorporating sparse chemical cross-linking of small molecules. The thermo-sensitive, NIR light-responsive, toughness and strength of the pure PNIPAM, PNIPAM-Graphene oxide(GO) and PNIPAM-GO-Zirconia(ZrO2) hydrogels were invesitgated. The introduction of GO induced PNIPAM the transformation from the thermosensitive to NIR light-responsive, and the oxidized groups of GO nanosheets could physically cross-link the PNIPAM chains to increase the toughness of the hydrogel networks. The loading capability and penetration resistance of PNIPAM-GO-ZrO2 composite hydrogel was obviously improved due to that the ZrO2 powder stabilize the hydrogel networks and strengthen the hydrogen bond interaction with the amide groups of PNIPAM chains compared with that of the pure PNIPAM and PNIPAM-GO, respectively.
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