化学
插入反应
天然产物
组合化学
选择性
立体化学
有机化学
催化作用
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2020-03-10
卷期号:31 (09): 838-844
被引量:5
标识
DOI:10.1055/s-0039-1691738
摘要
Insertion reactions of donor/donor carbenes have emerged from obscurity to become a versatile method for the synthesis of a variety of cyclic structures with excellent control of diastereo- and enantioselectivity. This Account describes the origin of this project as part of a natural product synthesis and the ensuing decade of reaction development that has resulted in new asymmetric methods as well as intriguing tangential observations.
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