Construction of natural polymeric imprinted materials and their applications in water treatment: A review

• Preparation of natural polymeric molecularly imprinted materials (MIMs). • Construction of microscopic identifying cavities in natural polymeric MIMs. • Fabrication of macroscopic visible condensed structures of natural polymeric MIMs. • Various applications of natural polymeric MIMs in water treatment. • Structure-activity relationship of natural polymeric MIMs. Molecularly imprinted materials (MIMs) have been widely used in various fields, including water treatment, chemical sensing, and biotechnology, because of their specific recognition and high selectivity. MIMs are usually obtained via two successive steps, namely, (1) copolymerization and crosslinking reactions of the preassembled complex of comonomers and a specific target compound (2) and thorough removal of template molecules. Some functional polymers are directly used as supporting materials and functional groups assembled with target compound are provided to simplify the preparation of MIMs. Natural polymers, such as chitosan, cyclodextrin, sodium alginate, starch, cellulose, lignin and their derivatives, are good candidates because of their environmentally friendly properties, low costs, and abundant active functional groups. In this study, different methods for the preparation of natural polymeric MIMs were reviewed in terms of the construction of microscopic binding cavities and macroscopic visible condensed structures with different shapes. Natural polymeric MIMs in water treatment applications, such as adsorption and detection of various pollutants from aqueous solutions, were summarized. Prospects on the development of novel and high-performance natural polymeric MIMs were discussed to overcome the difficulties in their preparation and applications.