析氧
氢氧化物
镍
电催化剂
催化作用
材料科学
无机化学
化学
化学工程
氧气
冶金
物理化学
电极
电化学
有机化学
工程类
作者
Chunlei Peng,Nian Ran,Gang Wan,Weixia Zhao,Zhuoran Kuang,Zheng Lü,Chengjun Sun,Jianjun Li,Luyao Wang,Hangrong Chen
出处
期刊:Chemsuschem
[Wiley]
日期:2020-01-21
卷期号:13 (4): 811-818
被引量:58
标识
DOI:10.1002/cssc.201902841
摘要
Nickel-iron layered double hydroxide (NiFe LDH) is a promising oxygen evolution reaction (OER) electrocatalyst under alkaline conditions. Much research has been performed to understand the structure-activity relationship of NiFe LDH under OER conditions. However, the specific role of the Fe species remains unclear and under debate. Herein, based on DFT calculations, it was discovered that the edge Fe sites show higher activity towards OER than either the edge Ni sites or lattice sites. Therefore, a facile acid-etching method was proposed to controllably induce the formation of edge Fe sites in NiFe LDH, and the obtained sample exhibited higher OER activity. X-ray absorption near edge structure and extended X-ray absorption fine structure analyses further revealed that the interaction of the edge Fe species with Ni is believed to contribute to the enhancement of the OER performance. This work provides a new understanding of the structure-activity relationship in NiFe LDH and offers a facile method for the design of efficient electrocatalysts in an alkaline environment.
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