木材气体发生器
合成气
煤气化
煤
工艺工程
燃烧
整体气化联合循环
环境科学
固体燃料
废物管理
煤燃烧产物
化学
工程类
氢
有机化学
作者
Naveed Ramzan,Shahid Naveed,Asma Ashraf,Jasira Usman,Hafeera Shabbir,Shawala Azhar
摘要
Gasification is a thermochemical transformation of solid fuel by partial oxidation into synthesis gas comprising of mainly carbon monoxide and hydrogen. Use of this syngas as fuel for gas turbines to generate electricity has enhanced the environmental acceptability of coal gasification. In this work a rigorous model of Coal gasification unit has been developed using the Gibbs free energy minimum method in the RGibbs model. RGibbs models the gasification and combustion reaction neglecting the hydrodynamic complexity of the gasifier. The devolatilization-pyrolsis stage is modeled using RYield model. RGibbs model determines the equilibrium composition of the products resulting from the many reactions that can occur. The influence of operating conditions (temperature and feed composition) on gasifier performance is investigated. The proposed gasification model improves the understanding of the process and can be used as a predictive tool at the optimization stage. ASPEN Plus is used as the simulation tool because it includes physical property models useful in solids handling.
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