Au Polyhedron Array with Tunable Crystal Facets by PVP‐Assisted Thermodynamic Control and Its Sharp Shape As Well As High‐Energy Exposed Planes Co‐Boosted SERS Activity

A route is developed for directly growing 2D Au polyhedron arrays with controllable exposed facets of polyhedron by utilizing the substrate-supported 2D Au quasi-spherical nanoparticle arrays as the Au seed arrays, which cannot be realized by traditional lithography. In the reaction system, polyvinyl pyrrolidone (PVP) plays a vital role in guiding the reduced Au atoms and stabilizing the substrate-supported Au seeds. More importantly, by thermodynamic control, PVP as a capping agent can further direct the formation of {111} facets. The key to guarantee the integrity and periodicity of array is a proper reduction of Au ions and low growth rate of crystal. Benefiting from the higher electric field intensity near the sharp vertexes and edges of Au polyhedra and the exposed {110} facets with high energy, the Au polyhedron array with {110} facets encasing polyhedron exhibits good, stable surface enhanced Raman scattering activity toward 4-aminothiophenol among the involved arrays. The proposed fabrication approach tremendously enriches the structural diversity of Au nanoarrays on substrates and greatly overcomes the shortcoming of traditional lithography.