The title compound, C21H23ClN2O7S2, is a representative of moderately active hydroxyacid synthase inhibitors. The structure has a sulfonylimine bond [—N=C(—SMe)—CH] and not sulfonylamino [—NH—C(—SMe)=C], contrary to expectations. There is a strong intramolecular hydrogen bond between the imine H and the acid carbonyl group, and a weaker one between the imine carbonyl group and a benzene H atom.