Construction of Novel Chiral NPN Ligands and the Application in Gold(I)‐Catalyzed Asymmetric Cycloaddition Reactions

Abstract This paper reports a novel chiral NPN ligand derived from the modification of Ming–Phos. This series of ligands possess advantages such as easy synthesis and convenient modification. Moreover, they exhibit excellent enantioselectivity in gold(I)‐catalyzed asymmetric [3 + 3] cycloaddition reactions.