Front Cover: Spiro‐Driven Ferroelectric Coordination Polymer Exhibiting Distinct Phase Transitions under Thermal and Pressure Stimuli (Angew. Chem. Int. Ed. 19/2025)

A spiro-conformation-driven neutral ferroelectric coordination polymer, [Cd(MEO)(SCN)2], is reported by Zi-Yi Du, Weizhao Cai, Rui-Kang Huang, and co-workers in their Communication (e202500027). This material features dual-stimuli-responsive phase transitions: a thermally activated ferroelectric transition via spiro-conformational flipping and a pressure-induced transition arising from helical chain deformation. This study showcases a rare example of a multi-responsive neutral ferroelectric system, advancing the design of molecular ferroelectrics via unconventional stimulus–response mechanisms.