Layered Potassium Vanadate K 0.5 V 2 O 5 as a Robust Cathode Material for Aqueous Zinc‐Ion Batteries

Layered vanadates are promising cathode materials for aqueous zinc-ion batteries (AZIBs). Herein, a layered potassium vanadate K_0.5V₂O₅ is reported as a promising cathode material for AZIBs. It provides a high reversible capacity of 471.1 mAh g^-1 with unprecedent cycle life at a harsh low rate of 0.21 C (90.2% capacity retention after 400 cycles, running time 150 days), remarkable rate capability and decent long-term cycling stability (no capacity decay after 1700 cycles). According to a series of tests, it is revealed that the energy storage mechanism of K_0.5V₂O₅ involves initial extraction of K⁺ followed by subsequent (de)intercalation of Zn²⁺/H⁺, in which the concomitant structure change and chemical state transition of vanadium possess high reversibility. Moreover, K_0.5V₂O₅ exhibits rapid Zn²⁺/H⁺ ion diffusion, favoring its rate capability. Additionally, K_0.5V₂O₅ also demonstrates excellent low-temperature adaptability, which can operate stably at -30 °C. The excellent electrochemical performance, facile preparation, and low cost of K_0.5V₂O₅ promise it as an attractive cathode candidate for practical AZIBs.