Solution-Growth Liquid-Phase Epitaxy of CsPbBr3 on NaCl by Optimizing the Substrate Dissolution

Since the earliest days of liquid-phase epitaxy (LPE) research, substrate stability has been a prerequisite for investigating nucleation and epitaxial growth. For flux- and melt-growth LPE, soluble substrates have always been viewed as problematic and difficult. However, solution-growth LPE transforms this disadvantage into a benefit by facilitating the creation of graded interfaces. In this study, we investigated the nucleation and growth of solution-grown LPE in the evaporation mode of soluble CsPbBr3 on freshly cleaved NaCl single-crystal substrates. Only two of the four main types of CsPbBr3 crystallization observed are epitaxial. The microscopic observation of composition gradients at the interface of CsPbBr3 grains and substrates reveals a promising opportunity to manipulate the lattice constant at the interface by simply controlling the temperature and concentration.