超级电容器
碳化
比表面积
电解质
多孔性
介孔材料
材料科学
碳纤维
电化学
化学工程
电流密度
复合材料
化学
电容
复合数
工程类
有机化学
电极
扫描电子显微镜
物理化学
物理
量子力学
催化作用
作者
Yutong Zhao,Jincheng Mu,Yuanyuan Wang,Yanxiu Liu,Huan Wang,Hua Song
标识
DOI:10.1007/s10854-023-09885-8
摘要
Here we report an effective and facile method for preparing porous carbons (CSCK-T-x) with highly developed hierarchical porosity for high-performance supercapacitor by one-step KOH activation of coconut shell carbon. The effects of carbonization temperature (T, °C) and KOH/C ratio (x) on the structure and electrochemical properties were studied systematically. As the KOH/C ratio and activation temperature increase, the SBET rapidly increases and then decreases and reaches a maximum (2143.6m2 g−1) at 800 °C with a KOH/C ratio of 2. Furthermore, CSCK-800-2 displayed abundant micropores and two concentrated mesopores at 4 nm and 14 nm. In a three-electrode test system, CSCK-800-2 exhibits a high specific capacitance of 317 F g−1 at a current density of 0.5 A g−1 and considerable rate retention of 68% at 20 A g−1. The symmetrical supercapacitor that was based on CSCK-800-2 showed a maximum energy density of 13.5 Wh kg−1 at 0.5 A g−1 with a superior cycling stability (99.7% of the capacitance retention after 10,000 cycles at 5 A g−1) in 6 M KOH electrolyte. The large specific surface area and unique hierarchical porosity of CSCK-800-2 enable it to have high ion-accessible surface and low-ion transport resistance. This one-step activation method provides an approach to convert biological waste into high-value hierarchical porous carbon material for electric double-layer capacitors.
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